- Gabriel W
- Oct 27, 2022
- 3 min read
Blog Post 4
10/21/2022
39O44’18” N 3O13’16” E
After a long drive through the arid and then surprisingly verdant stretches of Utah, we arrived at the campus of Utah State University, where we would stay at the student-run hotel. The next day, I would begin my internship with a surprisingly early wake-up time of 8:30. I know, I know, such a difficult thing to do… but I persevered.
I wandered through the campus for some time, trying to make sense of the map, until I finally found the chemistry building. After running laps around the building and finally meeting with the head of the chemistry lab, Dr. Leo, I was introduced to my mentor for the next week: Wenda Wu. Wenda cut quite a remarkable figure in black Nikes, pink shirt and pants, and a black hat—all covered by his lab coat. Wenda was a graduate student and PhD candidate working as a research assistant in the lab.
We first went down to what became my new favorite place on Earth: the college’s chemistry equipment supply shop. There were aisles of glassware, rows upon rows of reactantss and solvents, and of course, safety equipment, which is what had brought us there. I had a lab-coat fitting and left looking very dapper.
Wenda then brought me into the actual lab. Leo’s complex was broken up into two sections: the computer/office section and the actual lab. Thus far, I had only been in the computer lab, so as I stepped into the chemicals lab, I was arrested by the rows of fumehoods and the tables strewn with chemicals, beakers, and lab notes. Wenda ushered me to his own personal fumehood, with multiple beakers filled with all different brightly colored chemical, but instead of getting right to work, he wanted to give me some theory behind it all. He pulled down the glass front of the fumehood, whipped out hihs dry-erase marker, and began to give me a lecture about what the lab did. If we ever encountered a piece of knowledge I did not know, sometimes, we would go all the way back to the basics, so that by the end, I had a pretty concrete understanding of what the lab did.
Dr. Leo’s lab was working on discovering better, sustainable battery alternatives (batteries that require less toxic materials, can store more energy, and have longer lifespans). The specific battery type that Wenda was working on was called an aqueous redox flow battery, or ARFB. These batteries work on a simple reaction you see every day: oxidation. Whenever you see rust, for example, that is iron oxidizing. In certain circumstances, you could take that rust and reduce it back to iron. This oxidized-to-reduced-to-oxidized process is called a redox reaction (red, reduce; ox, oxidize). Everything has a state that it naturally wants to be in; one chemical might prefer to be reduced, while another might prefer to be oxidized. A redox reaction means that to move from one state to the other, the chemical must either gain or lose electrons. These ARFBs have one chemical that likes to be in a reduced state and another that likes to be oxidized, and they contain these chemicals in such a way that they do not touch each other. These specific chemicals oxidize and reduce when a current is applied; so, when you charge the battery, the chemical that prefers to be reduced oxidizes (and loses an electron), and the chemical that prefers to be oxidized reduces (and gains an electron). Those two chemicals now have an energy potential because they are in their nonpreferred states and want to get back to their preferred states. When you put this battery in a circuit to, say, turn on a lightbulb, the excess electrons from one chemical run through the circuit to the other chemical, reversing their states, making both chemicals happy, and powering the lightbulb.
As you might expect, it’s difficult to find a set of chemicals that like to oxidize and reduce, store up a specific amount of charge, can be suspended in water, and meet a whole boatload of other criteria. Dr. Leo’s lab works to synthesize chemicals and then test them in ARFBs to see if they could be the right ones.
We spent the whole week of my internship synthesizing one chemical set to test in an ARFB. Check out the below video to learn about the specific procedures that I mastered during my week synthesizing these chemicals in Dr. Leo’s lab.